Z Zibo Honors Chemical Co., Ltd Add: Wutai Industrial Zone, Linzi Dist.Zibo, Shandong,China Tel: +86-533-7167159 Fax: +86-533-7167159 P.C:255420 Http://www.honors.com.cn E-mail: honors@honors.com.cn MATERIAL SAFETY DATA SHEET OF MAC Section 1 、MANUFACTURE AND PRODUCTS a) Product Chemical name: Methallyl Chloride Synonyms:3-Chloro-2-methylpropene 2-Methylallyl Chloride b) Manufacturer Name: Zibo Honors Chemical Co., Ltd Address: Wutai, Linzi district, Zibo, Shandong, China Tel: +86-533-7167159 Fax: +86-533-7167159 +86-533-7661437 Contact in emergency: Sales dept. of Zibo Honors Chemical Co., Ltd. Tel: +86-533-7167159 Fax: +86-533-7167159 Section 2、PRODUCT INFOMATION Product Name------Methallyl Chloride Purity----------99.5% min Chemical Formula -----C4H7CL Structural Formula -----Molecular Weight-------90.55 CAS NO------563-47-3 Melting Point----- -80℃ Boiling Point-----72.17℃ Flash Point---- -12℃ UN Hazard Class-----3.2 UN NO.----2554 Section 3、 DANGEROUS GOODS CAUTION MAC is flammable (class one) and poisonous. It is fugitive; it is also at risk of burning and explosion to meet fire. It can burn or explode when reacting with strong oxidant. When burning, it can produce large quantity of poisonous gas, which will do great harm to environment and creature. It is harmful to human body and irritant to eyes, nose, throat, especially to lung and kidney. MOUSE 'S LD50 IS 395MG/KG. It is irritant to eye and skin; it can be absorbed by skin. Workers must wear protection clothes to avoid accident. Section 4、FIRST AID MEASURES EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, obtain medical attention. SKIN: Immediately flush with plenty of water while removing contaminated clothing and/or shoes, and thoroughly wash with soap and water. See a medical doctor immediately. INGESTION: Drink 1 or 2 glasses of water and induce vomiting by touching the back of the throat with a finger or by giving syrup of ipecac. Never induce vomiting or give anything by mouth to an unconscious person. See a medical doctor. INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain medical attention. NOTES TO MEDICAL DOCTOR: This product has moderate oral toxicity, and low dermal and inhalation toxicity. It is extremely irritating to the skin and minimally irritating to the eyes. Inhalation of this product may cause respiratory and mucous membrane irritation. Section 5、FIRE FIGHTING MEASURES FLASH POINT AND METHOD: -16°C FLAMMABLE LIMITS: 3.2% to 8.1% EXTINGUISH MEDIA: Foam, CO2 or dry chemical. Contain all runoff. EXPLOSION HAZARDS: Extremely flammable. Severe fire hazard when exposed to heat, flame or oxidizing material. Vapor may travel to an ignition source and flash back. Explosion hazard moderate when exposed to heat or flames. Confined vapors may present severe explosion FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full gear and self-contained breathing apparatus. Do not breathe smoke, gases or vapors HAZARDOUS DECOMPOSITION PRODUCTS: Vapors of chlorides and allylics. TO USE POWDER, FOAM, 1211,CARBON DEOXIDE FIRE EXTINGUISHER AND SAND. WATER NOT ALLOWED Section 6、ACCIDENTAL RELEASE MEASURES RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons and animals out of the area. Remove potential ignition sources. Isolate and post spill area. Wear protective clothing and respiratory protection as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons and animals out of the area. To clean and neutralize spill area, tools and equipment, wash with a solution of soap and water and add the solution to the drums of waste already collected. Dispose of drummed waste according to the method outlined in Section 13, "Disposal Considerations". Section 7、HANDLING AND STORAGE GENERAL PROCEDURES: Store in a cool, dry well-ventilated place. Do not use or store near heat, open flame or hot surfaces. Store in original containers only. Do not contaminate other materials, or allow this material to be contaminated, by improper storage or handling. Section 8、EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or mist may be emitted. Ventilate all transport vehicles prior to unloading. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles or a face shield with safety glasses. RESPIRATORY: For splash, spray or mist exposure wear, as a minimum, a properly fitted half-face or full-face air-purifying respirator with organic vapor cartridges (approved by U.S. NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection must be based on airborne concentrations. PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear laminate coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills, wear self contained breathing apparatus and fire protective clothing (turnout gear) because of the flammability hazard. Leather items - such as shoes, belts and watchbands - that become contaminated should be removed and decontaminated. Washing all work clothing before reuse (separately from household laundry). WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of eye or skin contamination. Wash skin prior to eating, drinking or using tobacco. Shower at the end of the workday. GLOVES: Wear chemical protective gloves made of materials such as neoprene or other impervious material. Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect regularly for leaks. Section 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Sweet APPEARANCE: Colorless liquid VAPOR PRESSURE: 102 mmHg @ 20°C BOILING POINT: 72°C (162°F) @ 760 mmHg SOLUBILITY IN WATER: Insoluble SPECIFIC GRAVITY: 0.926 @ 20°C (water = 1) MOLECULAR WEIGHT: 90.55 Section 10、STABILITY AND REACTIVITY CONDITIONS TO AVOID: Excessive heat and fire. POLYMERIZATION: Will not occur. Section 11、PACKING &TRANSPORT INFORMATION PROPER SHIPPING NAME: Methallyl Chloride PRIMARY HAZARD CLASS/DIVISION: 3 UN/NA NUMBER: UN2554 PACKING GROUP: II Handled with care to avoid leakage. And stored in dry, cool place .avoid shining. To be packaged with 200L PE drum or Iron drum (PVF inside).Net weight to be 180 kgs/drum, also can be packed in ISO-TANK (20mt net weight) Section 12、ECOLOGICAL INFORMATION None Section 13、DISPOSAL CONSIDERATIONS This product has moderate oral toxicity, and low dermal and inhalation toxicity. It is extremely irritating to the skin and minimally irritating to the eyes. Inhalation of this product may cause respiratory and mucous membrane irritation. Section 14、TRANSPORT INFORMATION US DOT Canada TDG Shipping Name: METHALLYL CHLORIDE METHALLYL CHLORIDE Hazard Class: 3.2 3.2 UN Number: UN2554 UN2554 Packing Group: II II Section 15、REGULATORY INFORMATION None Section 16、