Chapter 15 Review sheet Name Use this completion exercise to check your understanding of the concepts . and terms that are introduced in this chapter. Each blank can be completed with a term, short phrase, or number. Changes in the temperature and __1___ of a system alter the ___2___ 1. pressure of a solute. The extent to which a gas dissolves in a liquid is proportional 2. solubility to the __3__ of the gas in accordance with __4__ law. The solubility 3. pressure of a gas decreases with __5__ temperature. __6__ liquids tend to be 4. Henry’s soluble in water. Two liquids that are mutually soluble in each other 5. increasing are said to be __7__ . Generally the __8__ of a solid in water __9__ 6. polar with increasing temperature, but there are exceptions. The rate at which 7. miscible a solute __10__ is influenced by a number of factors, including the 8. solubility temperature of the solvent and the particle size of the solute The relative amounts of solute and __11__ in a __12__ can be described qualitatively as __13__ or concentrated. Quantitative units of concentration include molar concentration, percent concentration molal concentration, and mole fraction. The effects in solution of a nonvolatile __14__ on the properties of the solvent are called __15__ . They include __16__ point and vapor pressure __17__ and boiling point __18__. In each case, the magnitude of the effect is __19__ proportional to the number of solute molecules or ions present and is __20__ of the type of particle. Each solvent has a characteristic __21__ 9. increases 10. dissolves 11. solvent 12. solution 13. dilute 14. particles 15. colligative 16. freezing 17. lowering 18. elevation elevation constant and molal freezing-point __22__ constant. The colligative 19. directly properties are useful for demonstrating dissociation of solutes in solution 20. independent and in determining molecular masses. 21. boiling point 22. depression True False Classify each of these statements as always true, AT; sometimes true, ST; or never true, NT. AT 23. The rate at which a solute dissolves can be increased by grinding. NT_ 24. When added to 1000 g of water, 2 moles of a solute will increase the boiling point by 0.5l2°C. NT_ 25. One hundred mL of 1.0M sodium hydroxide solution is more concentrated than 1.0 L of 5M sodium hydroxide solution. AT_ 26. The amount of sodium hydroxide in 100 mL of 1.0M NaOH is less than that in 1.0 L of 5M NaOH solution. ST_ 27. As the temperature of a solvent decreases, the solubility of a solute increases. AT_ 28. A dilute solution contains less solute than required for equilibrium. NT 29. As an open bottle of a carbonated beverage cools, the concentration of dissolved carbon dioxide decreases. AT 30. Stirring a solute when adding it to a solvent should increase the rate of its dissolving. Problems Solve the following problems in the space provided. Show your work. 31. What mass of sucrose, C12H22011, is needed to make 300. mL of a 0.501M solution? 51.1g C12 H22 O11 32. What is the molarity of a solution that contains 212.5 g of sodium nitrate (NaNO3) in 3.0 liters of solution? .83M solution 33. You must prepare 320. mL of 0.75 M NaBr solution using 2.0M NaBr stock solution. How many mL of the stock solution should you use? 120mL Br stock solution 34. What is the freezing point of a solution that contains 2.0 mol of CaCl2in 800.g of water? Tf= -14 degrees C 35. Calculate the concentration in M of a solution which contains 0.40 mol NaCl dissolved into 1.5 L of solution. .27M solution 36. Calculate the molarity of a solution prepares when 20.2 g of KNO3 is dissolved into 250.mL of solution. .80M solution 37. Calculate the molality of a solution made by adding 34.8 g of K2SO4 to 800. g of water. .25m solution 38. Calculate the freezing and boiling point of a solution composed of 23.4 g of CaF2 dissolved in 175 g of water. Tf = -9.57 degrees C Tb=103 degrees C