Geophysics Research Letters Supporting Information for Ascent velocity and dynamics of the Fiumicino mud eruption, Rome, Italy A. Vona1, G. Giordano1, A. A. De Benedetti1, R. D’Ambrosio1, C. Romano1, M. Manga2 1: Dipartimento di Scienze, Università degli Studi Roma Tre, L.go San Leonardo Murialdo 1, 00146 Rome, Italy 2: Department of Earth and Planetary Science, University of California, Berkeley, CA 94720, USA Contents of this file Figure S1 to S2 Tables S1 to S2 Additional Supporting Information (Files uploaded separately) Captions for Movies S1 to S2 Introduction This data set contains physicochemical and rheological properties of the muds erupted in 2013 at Fiumicino. Bulk density of the mud was determined by helium pycnometry on sample aliquots. Water content and solid fraction were calculated from measurements of weight before and after drying in an oven. Electrical conductivity and pH of the aqueous solution were determined using a multiparametric probe. Mineralogy was determined through X-ray diffraction on sample powders. Size distribution of particles was measured by laser diffraction using a Mastersizer 2000 Particle Size Analyzer that measures the size range between 0.02 to 2000 microns. Out-sized ballistic clasts were characterized by measuring their size (by caliper) and their density (by helium pycnometry) (Fig. S1). Rheological measurements were performed using an Anton Paar RheolabQC concentric cylinder viscometer. 1 Figure S1. Schematic cross-section of the Fiumicino mud volcano. We infer that the conduits are cylindrical and evolved from boreholes drilled to depths of 40 m and 35 m. The likely source of clay in the erupted mud is the Holocene clayey interval between -20 and -40 m from ground level. The dashed line shows the bottom of the second borehole. Activity at vent 2 started as a consequence of destabilization of the thin clay material located near the bottom of the hole. There is no surface evidence for the formation of an expanding chamber in the Holocene clay layer, a mechanism proposed for other mud volcanoes (Rudolph et al. 2011; Shirzaei et al. 2015). Ballistics shown in Fig. S2 derive from ejection of manufacts from the shallow Holocene (historical) sands. 2 a) Size (cm)= 14 x 10 x 3 Density (g/cm 3)= 2.74 b) Size (cm)= 11 x 10 x 2 Density (g/cm 3)= 2.26 c) Size (cm)= 9 x 6 x 6 Density (g/cm 3)= 2.56 d) Figure S2. (a) Initial activity of Fiumicino mud volcano with ejection of out-sized ballistic clasts (photo taken on August 29, 2013); red circles indicate some of the large clasts selected for size and density determinations (b, c, d). 3 Aqueous Solution Samples Date Mud Density (g/cm3) Solid Fraction Mean pH Mean Conductivity (mS/cm) Salinity (ppt ) Volume Fraction (v) Grain Size Distribution (< 1.6 mm) Mode (m) d10 (m) d50 (m) d90 (m) St.Dev. FC 08 30 August 2013 1.4023 6.63 52.40 34.5 0.223 23.5431.97 1.49 11.99 47.21 2.64 FC 09 2 September 2013 1.3880 6.77 53.00 35.0 0.159 15.7221.35 1.46 19.71 39.13 2.45 FC 10 3 September 2013 1.3956 6.82 53.45 35.3 0.137 16.1226.20 1.54 9.71 40.95 2.48 FC 11 5 September 2013 1.2794 6.80 54.70 36.2 0.162 10.2414.63 1.52 8.61 35.53 2.33 FC 12 10 September 2013 1.2883 6.70 53.43 35.3 0.133 23.5431.97 1.92 14.49 51.05 2.45 FC 14 12 September 2013 1.2385 6.61 52.50 34.4 0.127 9.7313.56 1.49 8.65 36.89 2.36 FC 15 19 September 2013 1.1744 6.77 53.15 35.1 0.085 13.1718.55 1.60 9.73 41.35 2.20 FC 16 19 September 2013 1.1485 6.62 52.05 34.2 0.084 15.7221.35 1.68 10.57 42.54 2.42 Table S1. Table of physicochemical parameters of mud samples. 4 FC08 1.4022 0.223 1.38 Bulk Density, b (g/cm3) Volume Fraction,v d10 Grain Size Distribution (µm) FC16 1.1485 0.084 1.56 d50 10.96 9.78 d90 45.98 41.88 Herschel-Bulkley Fit Yield Stress, τy (Pa) 2.4996 0.0876 Consistency, K (Pa*s)n 0.8379 0.4813 Flow Index, n 0.3998 0.1975 R2 0.98 0.65 Applied Shear Rate (s-1) 4 Shear Stress (Pa) 3.89 (0.06) Viscosity (Pa s) 0.973 (0.015) Shear Stress (Pa) - Viscosity (Pa s) - 12 4.80 (0.09) 0.400 (0.008) 0.72 (0.05) 0.060 (0.004) 20 5.42 (0.28) 0.271 (0.014) 1.03 (0.09) 0.051 (0.005) 28 5.82 (0.05) 0.208 (0.002) 1.11 (0.05) 0.040 (0.002) 36 5.98 (0.09) 0.166 (0.002) 1.23 (0.11) 0.034 (0.003) 44 6.03 (0.05) 0.137 (0.001) 1.30 (0.02) 0.029 (0.001) 52 6.42 (0.27) 0.123 (0.005) 0.98 (0.09) 0.019 (0.002) 60 6.66 (0.08) 0.111 (0.001) 1.10 (0.02) 0.018 (0.001) 68 7.28 (0.09) 0.107 (0.001) 1.18 (0.05) 0.017 (0.001) 76 7.36 (0.02) 0.097 (0.001) 1.03 (0.05) 0.014 (0.001) 84 7.38 (0.20) 0.088 (0.002) 1.13 (0.03) 0.013 (0.001) 92 - - - - 1.33 (0.04) 0.014 (0.001) 100 - - - - 1.46 (0.03) 0.015 (0.001) Table S2. Details of rheology measurements. Movie S1. The Fiumicino mud eruption on 02 September 2013, nine days after the opening of the vent. Movie S2. The Fiumicino mud eruption on 17 September 2013, twenty-four days after the opening of the vent. 5 References Rudolph, M. L., L. Karlstrom, and M. Manga (2011), A prediction of the longevity of the Lusi mud eruption, Indonesia, Earth Planet. Sci. Lett., 308(1-2), 124–130, doi:10.1016/j.epsl.2011.05.037. Shirzaei, M., M. L. Rudolph, and M. Manga (2015), Deep and shallow sources for the Lusi mud eruption revealed by surface deformation, Geophys. Res. Lett., 42, doi:10.1002/2015GL064576. 6