The University of New South Wales School of Mechanical and Manufacturing Engineering MATS1110 - Introduction to Materials for Engineering Applications Sports Car Brake Pads Materials Selection Project Table of Contents Executive summary...................................................................................................................................... 3 Product Context............................................................................................................................................4 Component description and functions....................................................................................................... 4 Property Requirements................................................................................................................................5 Mechanical Property Requirements.........................................................................................................5 Non-Mechanical Property Requirements................................................................................................ 5 Candidate Materials.....................................................................................................................................7 Carbon ceramic composites.....................................................................................................................7 Metal alloys............................................................................................................................................. 8 Comparison of Mechanical Properties.................................................................................................... 8 Comparison of Non-mechanical Properties.............................................................................................9 Material Sourcing and Production/Process Costs................................................................................... 10 Preferred Candidate...................................................................................................................................11 Conclusion................................................................................................................................................... 11 Appendix..................................................................................................................................................... 12 Executive summary This report investigates the most suitable material for sports car brake pads, which endure extreme thermal and mechanical loads during high-speed braking. Three materials were evaluated Carbon-Carbon (C/C), Carbon-Silicon Carbide (C/SiC), and Copper-Tin (Cu–Sn) alloys - based on the brake pad’s mechanical and non-mechanical property requirements. While the Cu-Sn alloys were cheaper and easy to manufacture, their high-density and high-thermal conductivity made them unfitting for sports car applications. The carbon–ceramic composites demonstrated an overall better suitability, exhibiting excellent stiffness, strength and thermal stability. C/SiC was ultimately selected as the preferred material due to its higher oxidation temperature compared to C/C, which fell between the operating temperatures of sports car braking systems and presented risks such as degradation of material properties and braking failure. Product Context Braking pads are a critical component of a vehicle’s braking system as they are responsible for slowing vehicles down through converting kinetic energy into heat, by using friction against brake rotors. In high performance sports cars, brake pads operate under extreme environments as they endure intense thermal and mechanical loads to decelerate vehicles travelling at speeds upwards of 300 km/h. These exceptional demands make the selection of the material essential to ensure reliable, consistent and safe braking performance. As high performance sports cars are amongst the top-end of the car market, manufacturers and customers spare no expense for these pads in maximizing the car’s speed and handling capabilities Component description and functions A brake pad’s primary function within a vehicle's braking system is to slow it down by converting kinetic energy into heat. It is composed of a ‘friction material layer’ bonded to a steel backing plate with shims attached to minimise vibration and noise. The friction material is the working surface that acts against the brake disc to generate friction and braking torque. The steel backing plate provides structural support, transferring the force from hydraulic pistons to the friction material while braking. The shims act as a buffer to accommodate the expansion and contraction of the various metal components of the brake pad, reducing vibrations and maintaining stability when driving [1]. During braking, hydraulic pressure pushes the pad against the rotating disc converting kinetic energy into heat through friction at the mechanical interaction of the contact surfaces. This produces the braking torque necessary to slow down the car but it also produces high amounts of thermal energy. Consequently, the brake pad itself must be capable of withstanding the extreme temperatures, high loads, and wear and tear caused by braking. Even more so in sports cars where rapid deceleration from high speeds is expected and operating temperatures can reach the hundreds of degrees celsius. Property Requirements Mechanical Property Requirements As sports cars travel at extremely high speeds, the brake pads must be able to withstand the immense frictional forces and high temperatures generated during braking. Hence, the brake pad material must possess sufficient yield and compressive strength to avoid plastic deformation under these braking loads. Utilising a Porsche 911 brake test as baseline [2], a rough calculation on a high-performance sports car with a representative weight of 1500kg [3] was conducted. Assuming deceleration from 200 km/h, the required braking torque for each front wheel is approximately 2300 Nm [4]. Estimating the average pad contact pressure, with a pad coefficient of friction of 0.45 [5], a combined pad area of 0.010 m2 for both sides of the disc [6], and a rotor radius of 160mm [7]. The mean contact pressure can be expressed as: π 2300 π = µπ΄π = 0.45×0.010×0.16 = 3. 19 πππ Therefore, the brake pad material must maintain a compressive strength well above 3 MPa to prevent permanent deformation during high-load braking, with additional allowance for intense loads under repeated high-temperatures. Furthermore, fracture toughness is a crucial requirement for brake pads, as they undergo severe cyclical stresses and thermal gradients, making them susceptible to surface cracks and fractures. According to fracture mechanic principles, crack growth occurs when πΎ > πΎπ, where πΎπ is the material's fracture toughness [8]. Thus, brake pads must be made from a material with a high fracture toughness. Similarly, as brakes will endure thousands of braking cycles in their lifespan, a material with high fatigue strength is essential. A material with a fine-grained microstructure, high hardness and ductility would be most suitable [9], as they hinder dislocation movement and delay fatigue crack formation. The material should also exhibit a high elastic modulus to ensure maintained stiffness and stable frictional contact during high load braking [10], but not high enough to make them brittle. A study conducted by the University of Liverpool demonstrated that brake pads with a higher elastic modulus demonstrated reduced deformation, and more consistent braking performance under extreme conditions [11]. Thus, a material with a modulus above 100 GPa will allow structural stability and braking frictional consistency in performance car conditions. Non-Mechanical Property Requirements Sports car brakes operate under extreme thermal environments with core temperatures ranging from 450ºC to 600ºC, and peak surface temperatures of 800ºC [12]. Research shows that brake pads should have a low thermal conductivity to maintain safer caliper temperatures and stable breaking performance. Brake pads with high thermal conductivity have also demonstrated risk to brake fluid boiling and brake fade [13] Furthermore, as brake pads are exposed to the external environment, oxidisation and corrosion can significantly deteriorate braking performance. Excessive oxidisation produces thick brittle scales that break off, whilst corrosion induces surface pitting, both compromising friction, braking consistency and lifespan [14]. Therefore, selecting a material with corrosion and oxidisation resistance is essential. Most importantly, brakes must possess a high coefficient of friction to ensure consistent braking performance under both wet and dry conditions. High performance sport cars typically have brake pads with a coefficient of friction of around 0.4-0.5 [5] to provide reliability under heavy-load braking. Finally, a moderate density of 1.5 to 3 g/cm3 is the most optimal for a sports car to allow for a more light weight design for improved fuel efficiency and vehicle handling, without sacrificing wear resistance. Furthermore, studies have shown that a lower density friction material produces lower wear rates compared to higher density materials [15]. Property Requirements GRANTA Inputting these property requirements into GRANTA, a Fatigue strength vs Young’s modulus Ashby chart was plotted to identify which material groups are suitable for sport car brake pads; narrowing down potential materials. Figure 1: Young’s Modulus vs Fatigue Strength Ashby Chart [16] Candidate Materials Polymers are non-ideal due to comparatively poor strength and stiffness against metals and composites. Pure ceramics are also unfit as those classes of materials are too brittle. Metallic alloys and carbon composites are ideal for the brake pads, due to its high Young’s modulus, high service temperatures and fatigue properties. Carbon ceramic composites Suitable candidates for a brake pad would be C/SiC which is a fabrication of carbon and silicon [27], has the mechanical properties that satisfies the criteria of the brake pads function: fracture toughness, however the Young’s modulus is high relative to other carbides. The C/C composite, has a better fit Young’s modulus for the components function, and displays better fatigue strength than C/SiC, but costs more. C/SiC C/C Compressive strength (MPa) 112 212 Cost (USD$/kg) 1.5 10.5 Young’s Modulus (GPa) 375 160.2 4.6 5.4 1/2 Fracture Toughness (MPa π Fatigue Strength (MPa) ) 5 100, (2 × 10 Cycles) 6 180, (2 × 10 Cycles) Table 1: Mechanical properties of Carbon ceramics [19] [22] [29] [32] [18] [62] [63] Metal alloys Metal alloys also suit the conditions of the brake pads, these pure metals are alloyed together to increase the materials overall mechanical properties. A suitable material would be a sintered bronze alloy of principal element copper alloyed with tin and other metals (Cu-Sn) due to its typical metal mechanical properties and excellent thermal stability and corrosion resistance. Cu-Sn alloys Compressive strength (MPa) 330 Cost (USD$/kg) 2.2 Young’s Modulus (GPa) 117 1/2 Fracture Toughness (MPa π ) Fatigue Strength (MPa) 26 8 165, (10 Cycles) Table 2: Mechanical properties of Copper-Tin alloy [17], [22], [24], [19], [21], [64] Comparison of Mechanical Properties Carbon composites show the highest Young’s modulus compared to the metallic compounds, C/SiC shows very high stiffness (375 GPa), providing resistance to deformations under compression. C/C has a 6 middling Young’s modulus (160.2 GPa) and offers greater cyclic loading fatigue (180 MPa at 2 × 10 cycles) [25]. Cu-Sn alloys shows the most fatigue resistance under more cyclic loads and fracture 8 toughness (165 MPa at 10 cycles). Both C/SiC and Cu-Sn are relatively cheap to manufacture, while C/C ceramic is more expensive due to its production processes. Figure 2: Stress/Strain of C/SiC [24]. Figure 3: Stress/Strain of Cu/Sn alloys [33] Figure 4: Stress/Strain of C/C [54] Comparison of Non-mechanical Properties Both carbon composites offer low densities compared to the copper alloy (1.52, 2.05 < 9.4), The maximum service temperature of all materials are greater than 800-900β and so are all fit for the brake pads condition. Carbon/Carbon composites however suffer from a low oxidation resistance, and can react with oxygen above temperatures of 500β [37]. Cu-Sn Alloys C/Sic C/C Density (g/cc) 9.4 2.05 1.52 Thermal Conductivity (W/m×K) 111 38.89 22.722 Max Service Temperature (β) 935 1200 3000 Oxidation Temperature (β) 325 1100 500 Table 3: Thermal and oxidation properties of materials [26], [28], [31], [41]. The carbon ceramics are also chemically inert relative to the metals and so have an exceptional chemical resistance. While bronze also offers a higher corrosion resistance than its alloying metals [46], an oxide layer of patina can develop on the friction material [39]. This may lead to a reduced coefficient of friction or materials loss due to constant friction removing the oxide layer to be redeveloped [30]. Bronze alloy also arises the case of creating copper particles which can lead to pollution [28]. Material Sourcing and Production/Process Costs Carbon-ceramic brake pads and metallic brake pads differ substantially in terms of material sourcing, manufacturing complexity and costs. Carbon ceramics are difficult to source and manufacturing demands a complex multi-staged process that takes 20 days, which involves, carbon-fibre coating and fractioning, resin mixing and moulding, infiltration and sintering processes [50]. Although there have been several technological advancements in producing carbon-ceramic brake pads, reducing its manufacturing costs, high initial costs still remain a constraint [55]. With limited publicly disclosed information on how expensive the production cost is, a rough estimation of material costs can put this into perspective. Using the list of different pads shapes [6], we can calculate that an average pad would have the dimensions of 20mm thickness, and an area 70 cm2. Using the density of C/SiC found previously, with the average cost of this material at $1,800–$2,500/kg [52], just the material cost alone is roughly $700 USD. The expensive initial material cost and production process, justifies the high price tag with an average cost of $27000 USD for 4 sets of pads [56]. In contrast, metallic brake pads made with Cu-Sn alloys are manufactured through a highly automated process which involves mixing metal powders and fibres, hot pressing, curing and scorching [60]. This production process allows pads to be mass machined in a cost efficient manner [57]. With limited information on Cu-Sn production costs, in general metals are more widely available and affordable than carbon ceramics [58], these factors ultimately contribute to a cheaper general manufacturing cost (as seen in Table 4). Thus, making it a much cheaper process than carbon-ceramic manufacturing [58]. Table 4. Various metal Costs [51] These cheaper manufacturing costs are reflected in the pricing of Cu-Sn brake pads, with Amazon selling one set for around $45 USD [61]. Preferred Candidate Based on the established property requirements for sports car brake pads, C/SiC was chosen as the preferred material. This is because it excelled in all the required material properties with compressive strength, fatigue strength, fracture toughness, young’s modulus, oxidation temperature and thermal conductivity. C/SiC demonstrated better overall performance compared to Cu-Sn alloys, critically in thermal conductivity and density, where a low thermal conductivity is preferred to prevent the risk of brake fluid boiling and brake fade [13], and lower density allows for a lighter design. Moreover, although cheaper, sports cars are on the high-end of the market where customers and manufacturers will spare no expense on performance. Although C/C composites showed stronger suitability as a brake pad material with overall better properties than those of C/SiC. Their oxidation temperature of 500°C made them unsuitable for a sports car braking system, which operates at much higher temperatures. This is due to oxidation causing brake pads to “degrade their friction-wear and mechanical properties or even undergo braking failure” [59]. Thus, C/SiC was chosen as their oxidisation temperature is much greater than peak load temperatures faced by sports car braking systems. Conclusion In conclusion, as brake pads are vital to the overall performance and safety of sports cars, material requirements were identified based on their extreme operating conditions. Through research and comparison of Carbon-ceramic composites, with C/C and C/SiC, and the Cu-Sn metal alloy, these materials showed distinct advantages and disadvantages. While the metal alloy demonstrated more cost efficiency in the materials and manufacturing cost, it was out performed by the carbon-ceramics in material properties. Out of the carbon-ceramic composites, C/SiC proved to be more suitable for a sports car brake pad due to its high oxidation temperature, despite C/C providing overall better performance. Appendix [1] KEMSO. (2025). Understanding Brake Pad Parts: A Comprehensive Guide to Components, Fu. [online] Available at: https://www.kemsoracing.com/blogs/news/understanding-brake-pad-parts-a-comprehensive-guide-to-com ponents-function-and-maintenance [2] Dyer, E. (2023). 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