Vol. 35, No. 7 Journal of Semiconductors July 2014 Development of 10 kV 4H-SiC JBS diode with FGR termination Huang Runhua(黄润华)2; , Tao Yonghong(陶永洪)2 , Cao Pengfei(曹鹏飞)2 , Wang Ling(汪玲)2 , Chen Gang(陈刚)1 , Bai Song(柏松)1 , Li Rui(栗瑞)2 , Li Yun(李赟)1 , and Zhao Zhifei(赵志飞)1 1 Science 2 Nanjing and Technology on Monolithic Integrated Circuits and Modules Laboratory, Nanjing 210016, China Electronic Devices Institute, Nanjing 210016, China Abstract: The design, fabrication, and electrical characteristics of the 4H-SiC JBS diode with a breakdown voltage higher than 10 kV are presented. 60 floating guard rings have been used in the fabrication. Numerical simulations have been performed to select the doping level and thickness of the drift layer and the effectiveness of the edge termination technique. The n-type epilayer is 100 m in thickness with a doping of 6 1014 cm 3 . The on-state voltage was 2.7 V at JF D 13 A/cm2 . Key words: 4H-SiC; JBS diodes; edge termination; floating guard rings DOI: 10.1088/1674-4926/35/7/074005 EEACC: 2520 1. Introduction Because of the superior material properties, 4H silicon carbide (4H-SiC) is regarded as an ideal semiconductor for high temperatureŒ1 , high power, high radiation conditions. Nowadays, silicon is the most widely used semiconductor material in power devices, but devices in Si are limited in terms of its junction operating temperature at 125 ıC. Compared to devices in conventional semiconductor materials, SiC devices are able to operate at much higher temperatures. Due to its large bandgap (3.26 eV), SiC has negligible intrinsic carrier generation at high temperatures up to 300 ıC. It is a better candidate for high power applications. The PiN diode is a good choice because of its lower leakage current, but the forward voltage of the PiN diode is higher than the SBD (Schottky barrier diode) diode, and it is also limited by forward voltage degradation due to the material quality. The SBD diode will be commercialized before the PiN diode because of its lower forward voltage, and the reliability of the Schottky diode is not limited by the forward voltage drift. Due to the lower barrier height of the Schottky contact and the Schottky barrier height lowering that results under a high electric field, the 4H-SiC SBD diode presents a leakage current higher than the 4H-SiC PiN diode; however, the 4HSiC JBS (junction barrier Schottky) diodeŒ2 by the improvement of SBD exhibits a higher performance for a breakdown voltage lower than 10 kV. The demonstration of 4H-SiC SBD diodes up to 10.8 kV by using a multistep junction termination extension (MJTE) has been reportedŒ3; 4 . In most of the ultrahigh voltage power devices, JTE was widely used because of its high termination efficiencyŒ5 . A breakdown voltage of 21.7 kV was achieved by using a “space-modulated” JTE structure with a wide optimum JTE-dose window to tolerate the impact of the interface chargeŒ6 . But in the fabrication of the JBS diode, two implantations must be performed. The termination efficiency of floating guard ring (FGR) termination is lower than that of JTE, but the FGR can be formed together with the active region. In this paper, based on the previous studiesŒ7 9 , we report a 10 kV 4H-SiC diode with FGR termination. First, the simulations of FGR termination by finite elements method will be performed to study the ring’s spacing and interface charge between semiconductor and insulator. After a brief description of the technological process, diodes characterization will be presented for both forward and reverse modes. 2. Simulation The idea behind the JBS structures is to protect the Schottky barrier from the high electric field when the device is blocking reverse voltage. Current from the anode contact flows through a vertical region formed by two adjacent pC regions, through the lightly doped drift layer, and then to the cathode contact. The cross-sectional view of a 4H-SiC JBS diode is shown in Fig. 1. The distances of two adjacent pC regions and the width of pC are respectively 4.0 m and 2.0 m. Simulations by the finite elements method using the SILVACO ATLAS TCAD software have been performed to determine the parameters of the drift region such as thickness and doping without considering the termination. The following models have been used for breakdown analysis of the 10 kV 4H-SiC diode, the Shockley-Read-Hall (SRH) and Auger recombination model, avalanche generation, bandgap narrowing, impact ionization, and an incomplete ionization model. For a theoretical blocking voltage of 13300 V, the parameters: Wn D 100 m and Nd D 6 1014 cm 3 have been chosen. A safety margin in the blocking voltage has been taken to include the incertitudes with respect to SiC technology that is not yet quite mature. Floating guard ring termination is made of highly p-type rings, the doping level of the rings has no major influence on the termination efficiency. 60 guard rings with a width of 4 m were used in the simulations to reduce the amount of field crowding at the main junction by spreading the depletion layer past consecutively lower potential floating junctions. The total termination width is 450 m. The simulations show that † Corresponding author. Email: huruhu@hotmail.com Received 17 December 2013, revised manuscript received 18 February 2014 074005-1 © 2014 Chinese Institute of Electronics J. Semicond. 2014, 35(7) Huang Runhua et al. Fig. 1. Schematic device cross-sectional view of a 10000 V 4H-SiC JBS diode. the electric field distribution is very sensitive toward the ring’s spacing, so they must be carefully selected. Figure 2 shows the electric field distributions for reverse bias 10 kV for five different ring spacings. From the fist ring, the ring spacing increases gradually. The electric field distributions of termination have been optimized by the simulations. To avoid the breakdown at both ends of the termination, the termination T has been chosen. The electric field at the both ends is lower than that in the middle of the termination. A small ring spacing means that the electric field crowds at the end of the termination, because the n-type region between two rings will be depleted too fast. If the electric field around the main ring is lower, then the breakdown will happen at the last ring. T – 0.4 m and T – 0.6 m have been simulated (T ˙ x: all the ring spacings decrease or increase x m), and the results provide that if the decreasing of spacing is more than 0.4 m, the electric field at the last ring is higher than those in the middle of the termination, so that the breakdown will happen at the end of the termination. The electric field around the main ring increases with the ring spacing very slowly. Terminations T C 0.4 m and T C 0.6 m also have been simulated. With the increasing more than 0.6 m, the electric field around the main ring will be higher than those in the middle of the termination. The big spacing means a lower electric field at the end of the termination, so that the other parts of the termination must support a higher electric field. If the ring spacing is too big, the rings at the end of the termination will be lost. The breakdown voltage of the edge termination with floating guard rings is sensitive to the presence of an interface charge between the semiconductor and insulatorŒ8 . The simulations with different specific interface charge densities have been performed, and the electric field distributions are shown in Fig. 3. A negative charge will produce an extension of the depletion layer along the surface. If the negative charge density is 1 1012 cm 2 , the electric field at the last ring is higher than those in the middle of the termination; this is equivalent to a spacing decrease of 0.4 m. The positive charge has the opposite effect on the depletion layer at the surface; this is equivalent to an increase of the ring spacing. There is not an electric field at the end of termination, and the electric field crowds around the main ring. The rings at the end of the termination have been lost. The charge density can be determined to optimize ring spacing. The interface charge can produce a wide distribution in the breakdown voltages of the power devices. In the case of a negative charge, more floating field rings must be Fig. 2. Distribution of electric field for reverse bias 10 kV for different ring spacings. used to mitigate this problem. In the case of a positive charge, the number of rings with small ring spacing must be increased. 3. Fabrication The 10 kV 4H-SiC JBS diodes were fabricated on nC type conductivity 4H-SiC substrates, as shown in Fig. 4. An epitaxial n drift layer was grown on n-type substrates with a doping concentration of 6 1014 cm 3 , and the epitaxial thickness was 100 m to obtain a high breakdown voltage. The termina- 074005-2 J. Semicond. 2014, 35(7) Huang Runhua et al. Fig. 5. Measured reverse I –V characteristic for different terminations. parameter, respectively. The active JBS regions and edge termination were implemented by an optimized Al multiple hot implantation with a dose of 1.8 1018 cm 2 to a maximum energy of 550 keV. The ion implantation activation annealing was performed at 1650 ıC for 30 min in Ar. After that, a 0.2 m thick field SiO2 and a 0.3 m thick SiN were deposited on the surface as passivation. The anode and the cathode were formed by Ni. The Schottky contact annealing was carried out at 600 ıC for 10 min. 4. Characterization 4.1. Reverse characteristics Fig. 3. Distribution of electric field for reverse bias 10 kV for different specifies interface charge densities. Reverse performance has been characterized up to a leakage current of 200 A. We have obtained capable blocking of more than 10 kV with a ring spacing of termination T C 0.2 m, which is 77% of the ideal breakdown voltage. Figure 5 shows the reverse I –V characteristics of the fabricated 4H-SiC diode. The breakdown voltages of 7 kV and 8 kV are obtained respectively with the terminations T – 0.2 m and T . The termination efficiency increases with the ring spacing. According to the simulation results, the ring spacing is smaller than the optimal value, so part of the passivation layer at the end of termination is burned during the test. The ring spacing will decrease during the fabrication because of the implantation spreading and the mask etching. In the next work, the ring spacing and number will be increased to obtain a higher termination efficiency. 4.2. Forward characteristics The diode has been forward characterized at room temperature. To limit the device auto-heating, these characteristics have been obtained in pulse mode with a pulse width of 200 s. At 13 A/cm2 , the voltage drop is 2.7 V. A threshold voltage lower than 1.4 V has been achieved. Typical forward characteristics are presented respectively in Fig. 6. Fig. 4. Fabricated 10 kV 4H-SiC JBS diodes. tion with a total width of 450 m is composed of 60 guard rings with a width of 4.0 m. According to the simulation results, three different ring spacings of T 0.2 m, T and T C 0.2 m were used to determine the optimal termination 5. Summary 10 kV 4H-SiC JBS diodes have been fabricated. According to the simulation results, an epitaxial n drift layer (100 m, 074005-3 J. Semicond. 2014, 35(7) Huang Runhua et al. than 1.4 V. References Fig. 6. Forward I –V characteristics at room temperature. 6 1014 cm 3 / was grown on nC type conductivity 4HSiC substrates. The floating guard rings termination was simulated. Three different ring spacings were used. The simulations with different specifies interface charge densities have been performed to study the influence of interface charge on the termination electric field distribution. Reverse and forward characterizations were performed at room temperature. 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